Process / pipelineMass Transfer
Stefan-Maxwell Diffusion
The Stefan-Maxwell diffusion equation describes how multiple chemical species diffuse through each other in a mixture, accounting for interactions between all species pairs. Unlike Fick's law, which assumes species diffuse independently, Stefan-Maxwell theory captures the coupling that occurs when species with different diffusivities move at different rates. This is essential for analyzing gas separation, combustion, catalytic processes, and reactive distillation.
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Sources
- Reid, R. C., Prausnitz, J. M., & Poling, B. E. (1987). The Properties of Gases and Liquids (4th ed.). McGraw-Hill. ISBN: 978-0071247009
- Taylor, R., & Krishna, R. (1993). Multicomponent mass transfer. John Wiley & Sons. ISBN: 978-0471571032