Process / pipelineProcess Intensification
Reactive Distillation
Reactive distillation couples reaction and separation in a single column, where reactants are separated from products continuously while simultaneously undergoing reaction on catalytic trays. Pioneered in the 1990s by Klaus Sundmacher and others, this process intensification technique dramatically reduces capital cost, energy consumption, and environmental impact for suitable reactions. It is now industrially proven for esterification, hydration, and transesterification processes.
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Sources
- Sundmacher, K., & Kienle, A. (2003). Reactive Distillation: Status and Future Directions. Wiley-VCH. ISBN: 978-3-527-30623-9
- Siringi, S., & Malone, M. F. (1997). Design of reaction/distillation columns for esterification. Computers & Chemical Engineering, 21(12), 1223-1238. DOI: 10.1016/S0098-1354(97)00077-8 ↗
- James, M. J., Baur, R., & Krishna, R. (2000). Models for reactive distillation. AIChE Journal, 46(12), 2350-2365. DOI: 10.1002/aic.690461204 ↗