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슬래그 염기도×Ellingham Diagram×
분야광산공학광산공학
계열Process / pipelineProcess / pipeline
기원 연도19501944
창시자Pyrometallurgical PracticeHarold Jeffrey Torreyson Ellingham
유형Slag composition parameter for controlling roast/smelt conditionsGibbs free energy diagram for high-temperature reactions
원전Barnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗Ellingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗
별칭Basicity Index, Slag Chemistry ParameterGibbs Free Energy Diagram, High-Temperature Reduction Diagram
관련33
요약Slag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.The Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.
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