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Ellingham Diagram×슬래그 염기도×
분야광산공학광산공학
계열Process / pipelineProcess / pipeline
기원 연도19441950
창시자Harold Jeffrey Torreyson EllinghamPyrometallurgical Practice
유형Gibbs free energy diagram for high-temperature reactionsSlag composition parameter for controlling roast/smelt conditions
원전Ellingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Barnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗
별칭Gibbs Free Energy Diagram, High-Temperature Reduction DiagramBasicity Index, Slag Chemistry Parameter
관련33
요약The Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.Slag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.
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