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Slaggens Basicitet×Ellingham Diagram×Shrinking Core Model×
FagområdeMinedriftMinedriftMinedrift
FamilieProcess / pipelineProcess / pipelineProcess / pipeline
Oprindelsesår195019441976
OphavspersonPyrometallurgical PracticeHarold Jeffrey Torreyson EllinghamSzekely, Evans, and Sohn
TypeSlag composition parameter for controlling roast/smelt conditionsGibbs free energy diagram for high-temperature reactionsReaction kinetics model for solid-fluid reactions
Oprindelig kildeBarnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗Ellingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Szekely, J., Evans, J. W., & Sohn, H. Y. (1976). Gas-solid reactions. Academic Press, New York. link ↗
AliasserBasicity Index, Slag Chemistry ParameterGibbs Free Energy Diagram, High-Temperature Reduction DiagramShrinking Unreacted Core Model, SCM, Leaching Kinetics Model
Relaterede333
ResuméSlag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.The Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.The Shrinking Core Model, formalized by Szekely, Evans, and Sohn in 1976, describes the kinetics of chemical reactions between solid ore particles and surrounding fluids (leaching solutions, roasting gases). As the reaction proceeds from the particle surface inward, an unreacted core shrinks while products accumulate in a product layer. The model enables prediction of leaching times and optimization of hydrometallurgical processes.
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ScholarGateSammenlign metoder: Slag Basicity · Ellingham Diagram · Shrinking Core Model. Hentet 2026-06-18 fra https://scholargate.app/da/compare