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Ellingham Diagram×Shrinking Core Model×
FagområdeMinedriftMinedrift
FamilieProcess / pipelineProcess / pipeline
Oprindelsesår19441976
OphavspersonHarold Jeffrey Torreyson EllinghamSzekely, Evans, and Sohn
TypeGibbs free energy diagram for high-temperature reactionsReaction kinetics model for solid-fluid reactions
Oprindelig kildeEllingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Szekely, J., Evans, J. W., & Sohn, H. Y. (1976). Gas-solid reactions. Academic Press, New York. link ↗
AliasserGibbs Free Energy Diagram, High-Temperature Reduction DiagramShrinking Unreacted Core Model, SCM, Leaching Kinetics Model
Relaterede33
ResuméThe Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.The Shrinking Core Model, formalized by Szekely, Evans, and Sohn in 1976, describes the kinetics of chemical reactions between solid ore particles and surrounding fluids (leaching solutions, roasting gases). As the reaction proceeds from the particle surface inward, an unreacted core shrinks while products accumulate in a product layer. The model enables prediction of leaching times and optimization of hydrometallurgical processes.
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