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Shrinking Core Model×Ellingham Diagram×Slaggens Basicitet×
FagområdeMinedriftMinedriftMinedrift
FamilieProcess / pipelineProcess / pipelineProcess / pipeline
Oprindelsesår197619441950
OphavspersonSzekely, Evans, and SohnHarold Jeffrey Torreyson EllinghamPyrometallurgical Practice
TypeReaction kinetics model for solid-fluid reactionsGibbs free energy diagram for high-temperature reactionsSlag composition parameter for controlling roast/smelt conditions
Oprindelig kildeSzekely, J., Evans, J. W., & Sohn, H. Y. (1976). Gas-solid reactions. Academic Press, New York. link ↗Ellingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Barnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗
AliasserShrinking Unreacted Core Model, SCM, Leaching Kinetics ModelGibbs Free Energy Diagram, High-Temperature Reduction DiagramBasicity Index, Slag Chemistry Parameter
Relaterede333
ResuméThe Shrinking Core Model, formalized by Szekely, Evans, and Sohn in 1976, describes the kinetics of chemical reactions between solid ore particles and surrounding fluids (leaching solutions, roasting gases). As the reaction proceeds from the particle surface inward, an unreacted core shrinks while products accumulate in a product layer. The model enables prediction of leaching times and optimization of hydrometallurgical processes.The Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.Slag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.
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