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Ellingham Diagram×Slaggens Basicitet×
FagområdeMinedriftMinedrift
FamilieProcess / pipelineProcess / pipeline
Oprindelsesår19441950
OphavspersonHarold Jeffrey Torreyson EllinghamPyrometallurgical Practice
TypeGibbs free energy diagram for high-temperature reactionsSlag composition parameter for controlling roast/smelt conditions
Oprindelig kildeEllingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Barnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗
AliasserGibbs Free Energy Diagram, High-Temperature Reduction DiagramBasicity Index, Slag Chemistry Parameter
Relaterede33
ResuméThe Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.Slag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.
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