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| 异核单量子相干 (HSQC)× | 傅里叶变换离子回旋共振质谱× | |
|---|---|---|
| 领域 | 光谱学 | 光谱学 |
| 方法族 | Process / pipeline | Process / pipeline |
| 起源年份≠ | 1980 | 1974 |
| 提出者≠ | Anil Kumar | Alan Marshall |
| 类型≠ | Heteronuclear correlation sequence | Mass spectrometry technique |
| 开创性文献≠ | Bodenhausen, G., & Ruben, D. J. (1981). Natural abundance nitrogen-15 NMR by enhanced heteronuclear spectroscopy. Chemical Physics Letters, 69(2), 185-189. DOI ↗ | Comisarow, M. B., & Marshall, A. G. (1974). Fourier transform ion cyclotron resonance spectroscopy. Chemical Physics Letters, 25(2), 282-283. DOI ↗ |
| 别名 | HSQC NMR, 1H-13C HSQC, heteronuclear correlation | FT-ICR-MS, Fourier Transform ICR, ICR mass spectrometry |
| 相关 | 4 | 4 |
| 摘要≠ | Heteronuclear Single-Quantum Coherence (HSQC) is a 2D NMR technique that correlates proton and carbon-13 (or other heteronuclei) chemical shifts through one-bond coupling constants (1JHX). Developed in the early 1980s, HSQC rapidly became the workhorse of structural chemistry because it directly maps which carbons bear which protons, providing a comprehensive view of carbon skeleton connectivity and substitution patterns. | Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometry is an advanced analytical technique that combines magnetic confinement of ions with Fourier transform data processing to achieve exceptional mass accuracy and resolution. Developed by Comisarow and Marshall in 1974, FT-ICR-MS enables the determination of exact masses and elemental compositions of complex molecules, making it invaluable for environmental chemistry, metabolomics, petroleum characterization, and structural elucidation of unknowns. |
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