方法对比

	Hartree-Fock 方法	Möller-Plesset 摄动理论
领域	量子计算	量子计算
方法族	Machine learning	Machine learning
起源年份	1928	1934
提出者	Douglas Hartree and Vladimir Fock	Christian Möller and Milton Plesset
类型	Electronic structure method	Post-Hartree-Fock method
开创性文献	Fock, V. (1930). Näherungsmethode zur Lösung des quantenmechanischen Mehrkörperproblems. Zeitschrift für Physik, 61, 126–148.	Möller, C., Plesset, M. S. (1934). Note on an approximation treatment for many-electron systems. Physical Review, 46, 618–622.
别名	HF, self-consistent field	MP2, MP3, MP4
相关	4	3
摘要	The Hartree-Fock (HF) method is a foundational self-consistent field approach for solving the many-electron Schrödinger equation. Developed independently by Douglas Hartree and Vladimir Fock in the late 1920s, it approximates the ground state by assuming electrons move in an average field generated by all other electrons, enabling tractable quantum chemistry calculations.	Möller-Plesset perturbation theory is a post-Hartree-Fock method that systematically corrects the HF reference by treating electron correlation as a perturbation. Introduced in 1934, MP theory provides increasingly accurate energy estimates (MP2, MP3, MP4, ...) by expanding the correlation energy in orders of perturbation.