方法对比

	循环伏安法	RDE Koutecky-Levich
领域	光谱学	光谱学
方法族	Process / pipeline	Process / pipeline
起源年份	1964	1962
提出者	Randles Semyon Nicholson	Veniamin Levich
类型	Electrochemical technique	Electrochemical technique
开创性文献	Nicholson, R. S., & Shain, I. (1964). Electroanalytical chemistry. Analytical Chemistry, 36(4), 706-723.	Levich, V. G. (1962). Physicochemical Hydrodynamics. Prentice Hall.
别名	CV, cyclic voltammetry, electrochemistry	RDE, rotating disk electrode, Koutecky-Levich
相关	3	3
摘要	Cyclic Voltammetry (CV) is an electrochemical technique that measures redox reactions by varying the voltage applied to an electrode and monitoring the resulting current. Developed by Nicholson and Shain in 1964, CV is one of the most widely used electrochemical methods, providing rapid information about the redox potentials and electron-transfer kinetics of molecules and materials.	Rotating Disk Electrode (RDE) electrochemistry combined with Koutecky-Levich analysis is a powerful electrochemical technique that decouples diffusion-limited and kinetically limited electron-transfer processes. Developed by Levich in the 1960s, RDE enables determination of heterogeneous electron-transfer rate constants and mechanistic information by rotating an electrode to control mass transport.