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Теория кристаллического поля×Анализ лигандного поля×Анализ стереохимии×
ОбластьХимияХимияХимия
СемействоProcess / pipelineProcess / pipelineProcess / pipeline
Год появления19291960s1966
Автор методаHans BetheBrian Norman FiggisCahn, Ingold, & Prelog
ТипTheoretical modelTheoretical modelNomenclature system
Основополагающий источникBethe, H. (1929). Termaufspaltung in Kristallen. Annalen der Physik, 3(5), 133–208. DOI ↗Figgis, B. N. (1966). Introduction to Ligand Fields. Interscience Publishers. ISBN: 978-0471257356Cahn, R. S., Ingold, C., & Prelog, V. (1966). Specification of molecular chirality. Angewandte Chemie International Edition, 5(4), 385–415. DOI ↗
Другие названияCFT, crystal field, ligand field theoryligand field, LFT, ligand field theorystereochemical analysis, configuration assignment, chirality analysis
Связанные333
СводкаCrystal Field Theory (CFT) is a model that explains the electronic structure, color, magnetism, and reactivity of coordination complexes by considering how the electric field created by surrounding ligands perturbs the d-orbitals of a central metal ion. Developed by Hans Bethe in 1929 and refined throughout the 20th century, CFT is one of the most powerful tools for understanding inorganic chemistry.Ligand Field Theory (LFT) is an advanced model of metal-ligand bonding that combines crystal field theory with molecular orbital theory. Developed systematically by Brian Norman Figgis and others from the 1960s onward, LFT provides quantitative predictions of electronic structure, magnetism, spectra, and reactivity of coordination complexes, bridging the gap between qualitative crystal field arguments and rigorous quantum mechanics.Stereochemistry analysis is the systematic study of three-dimensional molecular structures, with emphasis on determining the spatial arrangement of atoms around chiral centers and assigning unambiguous names to stereoisomers. Formalized by Cahn, Ingold, and Prelog in 1966, the CIP (Cahn-Ingold-Prelog) rules provide an objective method for assigning R/S (or E/Z) nomenclature, enabling unambiguous communication of molecular structure.
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ScholarGateСравнение методов: Crystal Field Theory · Ligand Field Analysis · Stereochemistry Analysis. Получено 2026-06-20 из https://scholargate.app/ru/compare