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Теория кристаллического поля×Анализ стереохимии×
ОбластьХимияХимия
СемействоProcess / pipelineProcess / pipeline
Год появления19291966
Автор методаHans BetheCahn, Ingold, & Prelog
ТипTheoretical modelNomenclature system
Основополагающий источникBethe, H. (1929). Termaufspaltung in Kristallen. Annalen der Physik, 3(5), 133–208. DOI ↗Cahn, R. S., Ingold, C., & Prelog, V. (1966). Specification of molecular chirality. Angewandte Chemie International Edition, 5(4), 385–415. DOI ↗
Другие названияCFT, crystal field, ligand field theorystereochemical analysis, configuration assignment, chirality analysis
Связанные33
СводкаCrystal Field Theory (CFT) is a model that explains the electronic structure, color, magnetism, and reactivity of coordination complexes by considering how the electric field created by surrounding ligands perturbs the d-orbitals of a central metal ion. Developed by Hans Bethe in 1929 and refined throughout the 20th century, CFT is one of the most powerful tools for understanding inorganic chemistry.Stereochemistry analysis is the systematic study of three-dimensional molecular structures, with emphasis on determining the spatial arrangement of atoms around chiral centers and assigning unambiguous names to stereoisomers. Formalized by Cahn, Ingold, and Prelog in 1966, the CIP (Cahn-Ingold-Prelog) rules provide an objective method for assigning R/S (or E/Z) nomenclature, enabling unambiguous communication of molecular structure.
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  2. 2 Источники
  3. PUBLISHED
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ScholarGateСравнение методов: Crystal Field Theory · Stereochemistry Analysis. Получено 2026-06-20 из https://scholargate.app/ru/compare