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Electrochimie cu electrod rotativ (RDE) combinată cu analiza Koutecky-Levich×Cronoperoamperometrie×Voltametrie ciclică×
DomeniuSpectroscopieSpectroscopieSpectroscopie
FamilieProcess / pipelineProcess / pipelineProcess / pipeline
Anul apariției196219541964
Autorul originalVeniamin LevichPaul DelahayRandles Semyon Nicholson
TipElectrochemical techniqueElectrochemical techniqueElectrochemical technique
Sursa seminalăLevich, V. G. (1962). Physicochemical Hydrodynamics. Prentice Hall. link ↗Bard, A. J., & Faulkner, L. R. (2001). Electrochemical Methods: Fundamentals and Applications. John Wiley & Sons, 2nd edition. link ↗Nicholson, R. S., & Shain, I. (1964). Electroanalytical chemistry. Analytical Chemistry, 36(4), 706-723. link ↗
Denumiri alternativeRDE, rotating disk electrode, Koutecky-LevichCA, chronoamperometric methodCV, cyclic voltammetry, electrochemistry
Înrudite333
RezumatRotating Disk Electrode (RDE) electrochemistry combined with Koutecky-Levich analysis is a powerful electrochemical technique that decouples diffusion-limited and kinetically limited electron-transfer processes. Developed by Levich in the 1960s, RDE enables determination of heterogeneous electron-transfer rate constants and mechanistic information by rotating an electrode to control mass transport.Chronoamperometry (CA) is an electrochemical technique that measures current as a function of time when a potential step is applied to an electrode. Developed by Delahay in the 1950s, CA reveals diffusion-controlled electrochemical processes and enables determination of diffusion coefficients, surface coverage, and kinetic rate constants by analyzing the transient current decay.Cyclic Voltammetry (CV) is an electrochemical technique that measures redox reactions by varying the voltage applied to an electrode and monitoring the resulting current. Developed by Nicholson and Shain in 1964, CV is one of the most widely used electrochemical methods, providing rapid information about the redox potentials and electron-transfer kinetics of molecules and materials.
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ScholarGateCompară metode: RDE Koutecky-Levich · Chronoamperometry · Cyclic Voltammetry. Preluat la 2026-06-19 de pe https://scholargate.app/ro/compare