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Ecuația de stare Peng-Robinson×Analiza Pinch×Distilare reactivă×
DomeniuFizică aplicatăFizică aplicatăFizică aplicată
FamilieProcess / pipelineProcess / pipelineProcess / pipeline
Anul apariției197619781995
Autorul originalDing-Yu Peng and David Bernard RobinsonBodo Linnhoff, John FlowerKlaus Sundmacher
TipEquation of state; thermodynamic property correlationThermal design and optimization methodIntegrated reaction-separation process model
Sursa seminalăPeng, D. Y., & Robinson, D. B. (1976). A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15(1), 59-64. DOI ↗Linnhoff, B., & Flower, J. R. (1978). Synthesis of heat exchanger networks: I. Systematic generation of energy optimal networks. AIChE Journal, 24(4), 633-642. DOI ↗Sundmacher, K., & Kienle, A. (2003). Reactive Distillation: Status and Future Directions. Wiley-VCH. ISBN: 978-3-527-30623-9
Denumiri alternativePR-EOS, Peng-Robinson modelheat integration, pinch point method, process integrationintegrated distillation-reaction, reactive column, reaction with separation
Înrudite444
RezumatThe Peng-Robinson equation of state is a cubic model that describes the thermodynamic properties of pure fluids and mixtures. Introduced by Ding-Yu Peng and David Bernard Robinson in 1976, it improves upon earlier models (van der Waals, Redlich-Kwong) by better predicting compressibility factors and phase equilibria, especially near the critical point. It is widely used in petroleum engineering, chemical process design, and natural gas calculations.Pinch analysis is a systematic method for identifying the minimum energy requirements and optimal heat recovery opportunities in chemical processes. Developed by Bodo Linnhoff and John Flower in 1978, it graphically identifies the 'pinch point'—the most constrained part of the process where heating and cooling demands nearly balance. By targeting these bottlenecks, engineers can design energy-efficient heat exchanger networks and reduce operating costs dramatically.Reactive distillation couples reaction and separation in a single column, where reactants are separated from products continuously while simultaneously undergoing reaction on catalytic trays. Pioneered in the 1990s by Klaus Sundmacher and others, this process intensification technique dramatically reduces capital cost, energy consumption, and environmental impact for suitable reactions. It is now industrially proven for esterification, hydration, and transesterification processes.
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ScholarGateCompară metode: Peng-Robinson Equation of State · Pinch Analysis · Reactive Distillation. Preluat la 2026-06-20 de pe https://scholargate.app/ro/compare