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ボルタンメトリー×クーロメトリー×フローインジェクション分析×
分野分析化学分析化学分析化学
系統Process / pipelineProcess / pipelineProcess / pipeline
提唱年192219451975
提唱者Jaroslav HeyrovskyJames LinganeJaromir Ruzicka
種類electrochemical separation and analysiselectrochemical titrationcontinuous flow technique
原典Nicholson, R. S., & Shain, I. (1965). Theory of stationary electrode polarography for a chemical reaction coupled to electron transfer. Analytical Chemistry, 36(4), 706–723. link ↗Lingane, J. J. (1974). Electroanalytical Chemistry (2nd ed.). Interscience Publishers. ISBN: 978-0486409023Ruzicka, J., & Hansen, E. H. (1979). Flow injection analysis: Part 1. A new concept of fast continuous flow analysis. Analytica Chimica Acta, 106, 207–224. DOI ↗
別名electrochemical voltammetry, cyclic voltammetry, CV, differential pulse voltammetrycoulometric titration, electrochemical coulometry, amperes titrationFIA, sequential injection analysis, SIA, flow-based analysis
関連555
概要Voltammetry is an electrochemical analytical technique that studies chemical reactions and properties of substances by measuring the current response as the potential applied to an electrode is systematically varied. Developed by Jaroslav Heyrovsky in the 1920s (polarography), modern voltammetry has become essential for measuring redox potentials, detecting trace analytes, and investigating reaction mechanisms. Variants such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV) offer high sensitivity and selectivity for electrochemically active analytes.Coulometry is an electrochemical analytical method that determines the concentration of an analyte by measuring the total electric charge (in coulombs) required to oxidize or reduce the analyte completely at an electrode. Developed by James J. Lingane in the 1940s, coulometry is highly accurate because it is based on fundamental constants (Faraday's law) and does not require external standards or calibration curves. This method is particularly valuable for trace analysis, water determination, and analysis of reactive species.Flow injection analysis is an automated continuous-flow technique that rapidly injects a sample plug into a flowing stream of carrier solution, where it mixes with reagents and is detected online before reaching the detector. Developed by Jaromir Ruzicka and Elo Hansen in 1975, FIA revolutionized analytical chemistry by enabling rapid, high-throughput analysis with minimal reagent consumption and waste. Flow injection analysis is widely used in pharmaceutical, food, environmental, and clinical laboratories for routine quantitative analysis.
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ScholarGate手法を比較: Voltammetry · Coulometry · Flow Injection Analysis. 2026-06-19に以下より取得 https://scholargate.app/ja/compare