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スラグ塩基度×電解採取法×エリンガム線図×
分野鉱山工学鉱山工学鉱山工学
系統Process / pipelineProcess / pipelineProcess / pipeline
提唱年195018901944
提唱者Pyrometallurgical PracticeIndustrial Electrometallurgy PracticeHarold Jeffrey Torreyson Ellingham
種類Slag composition parameter for controlling roast/smelt conditionsElectrochemical metal extraction and purificationGibbs free energy diagram for high-temperature reactions
原典Barnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗Habashi, F. (2011). Electrometallurgy: principles, processes and materials. Metallurgical Transactions, 29(7), 1569-1589. link ↗Ellingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗
別名Basicity Index, Slag Chemistry ParameterElectrodeposition, Electrolytic ExtractionGibbs Free Energy Diagram, High-Temperature Reduction Diagram
関連333
概要Slag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.Electrowinning is an electrochemical process that extracts and refines metals from dilute leaching solutions by passing electric current through an electrolytic cell. Metal ions migrate to the cathode (negative electrode) and are reduced to pure metal, while impurities remain in solution. This process is essential for copper, zinc, cobalt, nickel, and gold refining, producing metals of exceptional purity.The Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.
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ScholarGate手法を比較: Slag Basicity · Electrowinning · Ellingham Diagram. 2026-06-18に以下より取得 https://scholargate.app/ja/compare