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| NMRスピンエコー× | FT-ICR Mass Spectrometry× | |
|---|---|---|
| 分野 | 分光学 | 分光学 |
| 系統 | Process / pipeline | Process / pipeline |
| 提唱年≠ | 1950 | 1974 |
| 提唱者≠ | Erwin Hahn | Alan Marshall |
| 種類≠ | Spectroscopic pulse sequence | Mass spectrometry technique |
| 原典≠ | Hahn, E. L. (1950). Spin echoes. Physical Review, 80(4), 580-594. DOI ↗ | Comisarow, M. B., & Marshall, A. G. (1974). Fourier transform ion cyclotron resonance spectroscopy. Chemical Physics Letters, 25(2), 282-283. DOI ↗ |
| 別名≠ | CPMG pulse sequence, spin-echo NMR | FT-ICR-MS, Fourier Transform ICR, ICR mass spectrometry |
| 関連 | 4 | 4 |
| 概要≠ | The spin-echo is a fundamental nuclear magnetic resonance (NMR) pulse sequence technique introduced by Erwin Hahn in 1950. It uses a 90-degree radiofrequency pulse followed by a 180-degree refocusing pulse to create an echo, effectively reversing the effects of magnetic field inhomogeneities and allowing accurate measurement of spin relaxation properties. This technique is essential in modern NMR spectroscopy for both one-dimensional and multidimensional experiments. | Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometry is an advanced analytical technique that combines magnetic confinement of ions with Fourier transform data processing to achieve exceptional mass accuracy and resolution. Developed by Comisarow and Marshall in 1974, FT-ICR-MS enables the determination of exact masses and elemental compositions of complex molecules, making it invaluable for environmental chemistry, metabolomics, petroleum characterization, and structural elucidation of unknowns. |
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