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配位子場解析×立体化学解析×
分野化学化学
系統Process / pipelineProcess / pipeline
提唱年1960s1966
提唱者Brian Norman FiggisCahn, Ingold, & Prelog
種類Theoretical modelNomenclature system
原典Figgis, B. N. (1966). Introduction to Ligand Fields. Interscience Publishers. ISBN: 978-0471257356Cahn, R. S., Ingold, C., & Prelog, V. (1966). Specification of molecular chirality. Angewandte Chemie International Edition, 5(4), 385–415. DOI ↗
別名ligand field, LFT, ligand field theorystereochemical analysis, configuration assignment, chirality analysis
関連33
概要Ligand Field Theory (LFT) is an advanced model of metal-ligand bonding that combines crystal field theory with molecular orbital theory. Developed systematically by Brian Norman Figgis and others from the 1960s onward, LFT provides quantitative predictions of electronic structure, magnetism, spectra, and reactivity of coordination complexes, bridging the gap between qualitative crystal field arguments and rigorous quantum mechanics.Stereochemistry analysis is the systematic study of three-dimensional molecular structures, with emphasis on determining the spatial arrangement of atoms around chiral centers and assigning unambiguous names to stereoisomers. Formalized by Cahn, Ingold, and Prelog in 1966, the CIP (Cahn-Ingold-Prelog) rules provide an objective method for assigning R/S (or E/Z) nomenclature, enabling unambiguous communication of molecular structure.
ScholarGateデータセット
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  2. 2 出典
  3. PUBLISHED
  1. v1
  2. 2 出典
  3. PUBLISHED

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ScholarGate手法を比較: Ligand Field Analysis · Stereochemistry Analysis. 2026-06-20に以下より取得 https://scholargate.app/ja/compare