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	ハートリー-フォック法	Moller-Plesset Perturbation Theory
分野	量子コンピューティング	量子コンピューティング
系統	Machine learning	Machine learning
提唱年	1928	1934
提唱者	Douglas Hartree and Vladimir Fock	Christian Möller and Milton Plesset
種類	Electronic structure method	Post-Hartree-Fock method
原典	Fock, V. (1930). Näherungsmethode zur Lösung des quantenmechanischen Mehrkörperproblems. Zeitschrift für Physik, 61, 126–148.	Möller, C., Plesset, M. S. (1934). Note on an approximation treatment for many-electron systems. Physical Review, 46, 618–622.
別名	HF, self-consistent field	MP2, MP3, MP4
関連	4	3
概要	The Hartree-Fock (HF) method is a foundational self-consistent field approach for solving the many-electron Schrödinger equation. Developed independently by Douglas Hartree and Vladimir Fock in the late 1920s, it approximates the ground state by assuming electrons move in an average field generated by all other electrons, enabling tractable quantum chemistry calculations.	Möller-Plesset perturbation theory is a post-Hartree-Fock method that systematically corrects the HF reference by treating electron correlation as a perturbation. Introduced in 1934, MP theory provides increasingly accurate energy estimates (MP2, MP3, MP4, ...) by expanding the correlation energy in orders of perturbation.