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サイクリックボルタンメトリー×クロノアンペロメトリー×RDE コウテツキー・レヴィッチ法×
分野分光学分光学分光学
系統Process / pipelineProcess / pipelineProcess / pipeline
提唱年196419541962
提唱者Randles Semyon NicholsonPaul DelahayVeniamin Levich
種類Electrochemical techniqueElectrochemical techniqueElectrochemical technique
原典Nicholson, R. S., & Shain, I. (1964). Electroanalytical chemistry. Analytical Chemistry, 36(4), 706-723. link ↗Bard, A. J., & Faulkner, L. R. (2001). Electrochemical Methods: Fundamentals and Applications. John Wiley & Sons, 2nd edition. link ↗Levich, V. G. (1962). Physicochemical Hydrodynamics. Prentice Hall. link ↗
別名CV, cyclic voltammetry, electrochemistryCA, chronoamperometric methodRDE, rotating disk electrode, Koutecky-Levich
関連333
概要Cyclic Voltammetry (CV) is an electrochemical technique that measures redox reactions by varying the voltage applied to an electrode and monitoring the resulting current. Developed by Nicholson and Shain in 1964, CV is one of the most widely used electrochemical methods, providing rapid information about the redox potentials and electron-transfer kinetics of molecules and materials.Chronoamperometry (CA) is an electrochemical technique that measures current as a function of time when a potential step is applied to an electrode. Developed by Delahay in the 1950s, CA reveals diffusion-controlled electrochemical processes and enables determination of diffusion coefficients, surface coverage, and kinetic rate constants by analyzing the transient current decay.Rotating Disk Electrode (RDE) electrochemistry combined with Koutecky-Levich analysis is a powerful electrochemical technique that decouples diffusion-limited and kinetically limited electron-transfer processes. Developed by Levich in the 1960s, RDE enables determination of heterogeneous electron-transfer rate constants and mechanistic information by rotating an electrode to control mass transport.
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ScholarGate手法を比較: Cyclic Voltammetry · Chronoamperometry · RDE Koutecky-Levich. 2026-06-19に以下より取得 https://scholargate.app/ja/compare