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吸着等温線(ランミュア・フレンドリッヒ)×CSTRモデル×
分野応用物理学応用物理学
系統Process / pipelineProcess / pipeline
提唱年19181962
提唱者Irving LangmuirOctave Levenspiel
種類Empirical and theoretical adsorption equilibrium modelMathematical model for continuous flow reactor
原典Langmuir, I. (1918). The adsorption of gases on plane surfaces of glass, mica, and platinum. Journal of the American Chemical Society, 40(9), 1361-1403. DOI ↗Levenspiel, O. (1999). Chemical Reaction Engineering (3rd ed.). John Wiley & Sons. ISBN: 978-0-471-25424-9
別名Langmuir isotherm, Freundlich isotherm, sorption equilibriumideal mixed reactor, back-mix reactor, CSTR
関連33
概要Adsorption isotherms describe the equilibrium uptake of a substance on a solid surface as a function of gas or solution phase concentration at constant temperature. The Langmuir isotherm (1918) and Freundlich isotherm (1906) are classical empirical models. The Langmuir model assumes monolayer coverage and is mechanistic; the Freundlich model is empirical and describes multilayer or heterogeneous adsorption. These isotherms are essential for designing separation processes (activated carbon filters, molecular sieves) and understanding pollutant sorption.The CSTR (Continuous Stirred-Tank Reactor) model describes the behavior of an ideal mixed reactor where fresh feed is continuously added, products are withdrawn, and contents are kept uniform by vigorous stirring. This fundamental model, formalized by Octave Levenspiel in the 1960s, is widely used to design and scale batch and continuous processes. Despite its simplicity, it captures essential dynamics of industrial reactors and is the baseline for process control and optimization.
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ScholarGate手法を比較: Adsorption Isotherm (Langmuir-Freundlich) · CSTR Model. 2026-06-18に以下より取得 https://scholargate.app/ja/compare