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| Equazione di Stato di Peng-Robinson× | UNIFAC× | |
|---|---|---|
| Campo | Fisica applicata | Fisica applicata |
| Famiglia | Process / pipeline | Process / pipeline |
| Anno di origine≠ | 1976 | 1975 |
| Ideatore≠ | Ding-Yu Peng and David Bernard Robinson | Aage Fredenslund, Russell Jones, John Prausnitz |
| Tipo≠ | Equation of state; thermodynamic property correlation | Activity coefficient model; predictive liquid-phase property method |
| Fonte seminale≠ | Peng, D. Y., & Robinson, D. B. (1976). A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15(1), 59-64. DOI ↗ | Fredenslund, A., Jones, R. L., & Prausnitz, J. M. (1975). Group-contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal, 21(6), 1086-1099. DOI ↗ |
| Alias | PR-EOS, Peng-Robinson model | UNIFAC predictive model, UNIQUAC functional-group contribution |
| Correlati≠ | 4 | 3 |
| Sintesi≠ | The Peng-Robinson equation of state is a cubic model that describes the thermodynamic properties of pure fluids and mixtures. Introduced by Ding-Yu Peng and David Bernard Robinson in 1976, it improves upon earlier models (van der Waals, Redlich-Kwong) by better predicting compressibility factors and phase equilibria, especially near the critical point. It is widely used in petroleum engineering, chemical process design, and natural gas calculations. | UNIFAC (Universal Functional-group Activity Coefficient) is a predictive model for liquid-phase activity coefficients of multicomponent mixtures. Developed by Fredenslund, Jones, and Prausnitz in 1975, it decomposes molecules into functional groups and uses group interaction parameters to estimate non-ideal behavior. UNIFAC is revolutionary because it can predict phase equilibria for mixtures never experimentally measured, making it invaluable for process design and chemical engineering. |
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