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	Metodo di Hartree-Fock	Teoria delle perturbazioni di Möller-Plesset
Campo	Calcolo quantistico	Calcolo quantistico
Famiglia	Machine learning	Machine learning
Anno di origine	1928	1934
Ideatore	Douglas Hartree and Vladimir Fock	Christian Möller and Milton Plesset
Tipo	Electronic structure method	Post-Hartree-Fock method
Fonte seminale	Fock, V. (1930). Näherungsmethode zur Lösung des quantenmechanischen Mehrkörperproblems. Zeitschrift für Physik, 61, 126–148.	Möller, C., Plesset, M. S. (1934). Note on an approximation treatment for many-electron systems. Physical Review, 46, 618–622.
Alias	HF, self-consistent field	MP2, MP3, MP4
Correlati	4	3
Sintesi	The Hartree-Fock (HF) method is a foundational self-consistent field approach for solving the many-electron Schrödinger equation. Developed independently by Douglas Hartree and Vladimir Fock in the late 1920s, it approximates the ground state by assuming electrons move in an average field generated by all other electrons, enabling tractable quantum chemistry calculations.	Möller-Plesset perturbation theory is a post-Hartree-Fock method that systematically corrects the HF reference by treating electron correlation as a perturbation. Introduced in 1934, MP theory provides increasingly accurate energy estimates (MP2, MP3, MP4, ...) by expanding the correlation energy in orders of perturbation.