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Analyse de la symétrie moléculaire×Analyse du champ des ligands×
DomaineChimieChimie
FamilleProcess / pipelineProcess / pipeline
Année d'origine1960s1960s
Auteur d'origineF. Albert CottonBrian Norman Figgis
TypeMathematical frameworkTheoretical model
Source fondatriceCotton, F. A. (1990). Chemical Applications of Group Theory (3rd ed.). John Wiley & Sons. ISBN: 978-0471510949Figgis, B. N. (1966). Introduction to Ligand Fields. Interscience Publishers. ISBN: 978-0471257356
Aliaspoint group analysis, symmetry operations, group theoryligand field, LFT, ligand field theory
Apparentées33
RésuméMolecular symmetry analysis is the systematic application of group theory to understand the structure, bonding, spectroscopy, and reactivity of molecules. Developed comprehensively by F. Albert Cotton and others from the 1960s onward, this framework uses the mathematical properties of molecular symmetry to predict allowed electronic transitions, molecular orbital shapes, vibrational modes, and reaction pathways.Ligand Field Theory (LFT) is an advanced model of metal-ligand bonding that combines crystal field theory with molecular orbital theory. Developed systematically by Brian Norman Figgis and others from the 1960s onward, LFT provides quantitative predictions of electronic structure, magnetism, spectra, and reactivity of coordination complexes, bridging the gap between qualitative crystal field arguments and rigorous quantum mechanics.
ScholarGateJeu de données
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  3. PUBLISHED
  1. v1
  2. 2 Sources
  3. PUBLISHED

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ScholarGateComparer des méthodes: Molecular Symmetry Analysis · Ligand Field Analysis. Consulté le 2026-06-19 sur https://scholargate.app/fr/compare