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Diagramme d'Ellingham×Électroextraction×Basicité des scories×
DomaineGénie minierGénie minierGénie minier
FamilleProcess / pipelineProcess / pipelineProcess / pipeline
Année d'origine194418901950
Auteur d'origineHarold Jeffrey Torreyson EllinghamIndustrial Electrometallurgy PracticePyrometallurgical Practice
TypeGibbs free energy diagram for high-temperature reactionsElectrochemical metal extraction and purificationSlag composition parameter for controlling roast/smelt conditions
Source fondatriceEllingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Habashi, F. (2011). Electrometallurgy: principles, processes and materials. Metallurgical Transactions, 29(7), 1569-1589. link ↗Barnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗
AliasGibbs Free Energy Diagram, High-Temperature Reduction DiagramElectrodeposition, Electrolytic ExtractionBasicity Index, Slag Chemistry Parameter
Apparentées333
RésuméThe Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.Electrowinning is an electrochemical process that extracts and refines metals from dilute leaching solutions by passing electric current through an electrolytic cell. Metal ions migrate to the cathode (negative electrode) and are reduced to pure metal, while impurities remain in solution. This process is essential for copper, zinc, cobalt, nickel, and gold refining, producing metals of exceptional purity.Slag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.
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ScholarGateComparer des méthodes: Ellingham Diagram · Electrowinning · Slag Basicity. Consulté le 2026-06-18 sur https://scholargate.app/fr/compare