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Électroextraction×Diagramme d'Ellingham×Modèle du noyau shrinking×
DomaineGénie minierGénie minierGénie minier
FamilleProcess / pipelineProcess / pipelineProcess / pipeline
Année d'origine189019441976
Auteur d'origineIndustrial Electrometallurgy PracticeHarold Jeffrey Torreyson EllinghamSzekely, Evans, and Sohn
TypeElectrochemical metal extraction and purificationGibbs free energy diagram for high-temperature reactionsReaction kinetics model for solid-fluid reactions
Source fondatriceHabashi, F. (2011). Electrometallurgy: principles, processes and materials. Metallurgical Transactions, 29(7), 1569-1589. link ↗Ellingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Szekely, J., Evans, J. W., & Sohn, H. Y. (1976). Gas-solid reactions. Academic Press, New York. link ↗
AliasElectrodeposition, Electrolytic ExtractionGibbs Free Energy Diagram, High-Temperature Reduction DiagramShrinking Unreacted Core Model, SCM, Leaching Kinetics Model
Apparentées333
RésuméElectrowinning is an electrochemical process that extracts and refines metals from dilute leaching solutions by passing electric current through an electrolytic cell. Metal ions migrate to the cathode (negative electrode) and are reduced to pure metal, while impurities remain in solution. This process is essential for copper, zinc, cobalt, nickel, and gold refining, producing metals of exceptional purity.The Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.The Shrinking Core Model, formalized by Szekely, Evans, and Sohn in 1976, describes the kinetics of chemical reactions between solid ore particles and surrounding fluids (leaching solutions, roasting gases). As the reaction proceeds from the particle surface inward, an unreacted core shrinks while products accumulate in a product layer. The model enables prediction of leaching times and optimization of hydrometallurgical processes.
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ScholarGateComparer des méthodes: Electrowinning · Ellingham Diagram · Shrinking Core Model. Consulté le 2026-06-18 sur https://scholargate.app/fr/compare