Compara mètodes

	Destil·lació reactiva	UNIFAC
Camp	Física aplicada	Física aplicada
Família	Process / pipeline	Process / pipeline
Any d'origen	1995	1975
Autor original	Klaus Sundmacher	Aage Fredenslund, Russell Jones, John Prausnitz
Tipus	Integrated reaction-separation process model	Activity coefficient model; predictive liquid-phase property method
Font seminal	Sundmacher, K., & Kienle, A. (2003). Reactive Distillation: Status and Future Directions. Wiley-VCH. ISBN: 978-3-527-30623-9	Fredenslund, A., Jones, R. L., & Prausnitz, J. M. (1975). Group-contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal, 21(6), 1086-1099.
Àlies	integrated distillation-reaction, reactive column, reaction with separation	UNIFAC predictive model, UNIQUAC functional-group contribution
Relacionats	4	3
Resum	Reactive distillation couples reaction and separation in a single column, where reactants are separated from products continuously while simultaneously undergoing reaction on catalytic trays. Pioneered in the 1990s by Klaus Sundmacher and others, this process intensification technique dramatically reduces capital cost, energy consumption, and environmental impact for suitable reactions. It is now industrially proven for esterification, hydration, and transesterification processes.	UNIFAC (Universal Functional-group Activity Coefficient) is a predictive model for liquid-phase activity coefficients of multicomponent mixtures. Developed by Fredenslund, Jones, and Prausnitz in 1975, it decomposes molecules into functional groups and uses group interaction parameters to estimate non-ideal behavior. UNIFAC is revolutionary because it can predict phase equilibria for mixtures never experimentally measured, making it invaluable for process design and chemical engineering.