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| Phương pháp thêm chuẩn× | Quang phổ phát xạ plasma cặp cảm ứng× | |
|---|---|---|
| Lĩnh vực | Hóa phân tích | Hóa phân tích |
| Họ | Process / pipeline | Process / pipeline |
| Năm ra đời≠ | 1920s | 1964 |
| Người khởi xướng≠ | Analytical chemistry practice | Stanley Greenfield |
| Loại≠ | matrix-compensating calibration technique | multi-element analysis technique |
| Công trình gốc≠ | Harris, D. C. (2010). Quantitative Chemical Analysis (8th ed.). Freeman. ISBN: 978-1429218153 | Greenfield, S., Jones, I. L., & Berry, C. T. (1968). High-pressure plasma jet source for use in atomic spectroscopy. Analyst, 93(1108), 694–697. link ↗ |
| Tên gọi khác≠ | spiking method, known-addition method, matrix matching | ICP-OES, ICP-AES, ICP-MS, plasma emission spectroscopy |
| Liên quan | 5 | 5 |
| Tóm tắt≠ | The standard addition method is a quantitative analytical technique that determines the concentration of an unknown analyte by measuring the response before and after adding a known quantity of the analyte (a standard) to the sample itself. This approach compensates for matrix effects and interference from other sample components, making it invaluable when analyzing complex matrices (biological fluids, environmental samples, geological materials) where the sample composition profoundly affects the measured signal. The standard addition method is widely recognized in analytical chemistry as a primary quantification strategy when external calibration is compromised by matrix variability. | Inductively coupled plasma spectrometry is a powerful multi-element analytical technique that ionizes a sample in a high-temperature plasma and measures the emitted light (ICP-OES) or ion masses (ICP-MS) to determine elemental concentrations. Developed in the 1960s by Stanley Greenfield, ICP techniques have become the standard for trace element analysis across environmental, geological, biological, and industrial fields. The method combines exceptional sensitivity, wide dynamic range, and the ability to analyze dozens of elements simultaneously. |
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