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Chưng cất phản ứng×UNIFAC×
Lĩnh vựcVật lý ứng dụngVật lý ứng dụng
HọProcess / pipelineProcess / pipeline
Năm ra đời19951975
Người khởi xướngKlaus SundmacherAage Fredenslund, Russell Jones, John Prausnitz
LoạiIntegrated reaction-separation process modelActivity coefficient model; predictive liquid-phase property method
Công trình gốcSundmacher, K., & Kienle, A. (2003). Reactive Distillation: Status and Future Directions. Wiley-VCH. ISBN: 978-3-527-30623-9Fredenslund, A., Jones, R. L., & Prausnitz, J. M. (1975). Group-contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal, 21(6), 1086-1099. DOI ↗
Tên gọi khácintegrated distillation-reaction, reactive column, reaction with separationUNIFAC predictive model, UNIQUAC functional-group contribution
Liên quan43
Tóm tắtReactive distillation couples reaction and separation in a single column, where reactants are separated from products continuously while simultaneously undergoing reaction on catalytic trays. Pioneered in the 1990s by Klaus Sundmacher and others, this process intensification technique dramatically reduces capital cost, energy consumption, and environmental impact for suitable reactions. It is now industrially proven for esterification, hydration, and transesterification processes.UNIFAC (Universal Functional-group Activity Coefficient) is a predictive model for liquid-phase activity coefficients of multicomponent mixtures. Developed by Fredenslund, Jones, and Prausnitz in 1975, it decomposes molecules into functional groups and uses group interaction parameters to estimate non-ideal behavior. UNIFAC is revolutionary because it can predict phase equilibria for mixtures never experimentally measured, making it invaluable for process design and chemical engineering.
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ScholarGateSo sánh phương pháp: Reactive Distillation · UNIFAC. Truy cập ngày 2026-06-18 từ https://scholargate.app/vi/compare