Сравнение методов

	Модель реактора идеального вытеснения	UNIFAC
Область	Прикладная физика	Прикладная физика
Семейство	Process / pipeline	Process / pipeline
Год появления	1962	1975
Автор метода	Octave Levenspiel	Aage Fredenslund, Russell Jones, John Prausnitz
Тип	Mathematical model for plug-flow reactor	Activity coefficient model; predictive liquid-phase property method
Основополагающий источник	Levenspiel, O. (1999). Chemical Reaction Engineering (3rd ed.). John Wiley & Sons. ISBN: 978-0-471-25424-9	Fredenslund, A., Jones, R. L., & Prausnitz, J. M. (1975). Group-contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal, 21(6), 1086-1099.
Другие названия	ideal tubular reactor, plug-flow model, PFR	UNIFAC predictive model, UNIQUAC functional-group contribution
Связанные	3	3
Сводка	The PFR (Plug Flow Reactor) model describes the behavior of a tubular reactor in which fluid elements move through as distinct plugs with no axial mixing. Fluid at the inlet is freshly unreacted; as it travels downstream, reactions progress. This idealized model, formalized by Octave Levenspiel alongside CSTR theory, is the opposite extreme: while CSTRs are fully mixed, PFRs have no axial mixing. In practice, PFRs achieve higher conversion than CSTRs for the same residence time and are widely used in the chemical and petroleum industries.	UNIFAC (Universal Functional-group Activity Coefficient) is a predictive model for liquid-phase activity coefficients of multicomponent mixtures. Developed by Fredenslund, Jones, and Prausnitz in 1975, it decomposes molecules into functional groups and uses group interaction parameters to estimate non-ideal behavior. UNIFAC is revolutionary because it can predict phase equilibria for mixtures never experimentally measured, making it invaluable for process design and chemical engineering.