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Metoda Hartreego-Focka×Sprzężone klastery CCSD×
DziedzinaObliczenia kwantoweObliczenia kwantowe
RodzinaMachine learningMachine learning
Rok powstania19281966
TwórcaDouglas Hartree and Vladimir FockJiri Cizek
TypElectronic structure methodElectronic correlation method
Źródło pierwotneFock, V. (1930). Näherungsmethode zur Lösung des quantenmechanischen Mehrkörperproblems. Zeitschrift für Physik, 61, 126–148. link ↗Cizek, J. (1966). On the correlation problem in atomic and molecular systems. Journal of Chemical Physics, 45, 4256–4266. link ↗
Inne nazwyHF, self-consistent fieldCCSD, CCSD(T)
Pokrewne43
PodsumowanieThe Hartree-Fock (HF) method is a foundational self-consistent field approach for solving the many-electron Schrödinger equation. Developed independently by Douglas Hartree and Vladimir Fock in the late 1920s, it approximates the ground state by assuming electrons move in an average field generated by all other electrons, enabling tractable quantum chemistry calculations.Coupled Cluster theory, particularly CCSD (Singles and Doubles) and CCSD(T) with perturbative triples, is one of the most accurate methods for molecular electronic structure. Developed by Jiri Cizek in 1966, CC theory treats the ground state wave function as an exponential of excitation operators applied to the Hartree-Fock reference, enabling systematic treatment of electron correlation with guaranteed size consistency.
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ScholarGatePorównaj metody: Hartree-Fock Method · Coupled Cluster CCSD. Pobrano 2026-06-18 z https://scholargate.app/pl/compare