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NMR Spin-Echo×FT-ICR Mass Spectrometry×
VakgebiedSpectroscopieSpectroscopie
FamilieProcess / pipelineProcess / pipeline
Jaar van ontstaan19501974
GrondleggerErwin HahnAlan Marshall
TypeSpectroscopic pulse sequenceMass spectrometry technique
Oorspronkelijke bronHahn, E. L. (1950). Spin echoes. Physical Review, 80(4), 580-594. DOI ↗Comisarow, M. B., & Marshall, A. G. (1974). Fourier transform ion cyclotron resonance spectroscopy. Chemical Physics Letters, 25(2), 282-283. DOI ↗
AliassenCPMG pulse sequence, spin-echo NMRFT-ICR-MS, Fourier Transform ICR, ICR mass spectrometry
Verwant44
SamenvattingThe spin-echo is a fundamental nuclear magnetic resonance (NMR) pulse sequence technique introduced by Erwin Hahn in 1950. It uses a 90-degree radiofrequency pulse followed by a 180-degree refocusing pulse to create an echo, effectively reversing the effects of magnetic field inhomogeneities and allowing accurate measurement of spin relaxation properties. This technique is essential in modern NMR spectroscopy for both one-dimensional and multidimensional experiments.Fourier Transform Ion Cyclotron Resonance (FT-ICR) mass spectrometry is an advanced analytical technique that combines magnetic confinement of ions with Fourier transform data processing to achieve exceptional mass accuracy and resolution. Developed by Comisarow and Marshall in 1974, FT-ICR-MS enables the determination of exact masses and elemental compositions of complex molecules, making it invaluable for environmental chemistry, metabolomics, petroleum characterization, and structural elucidation of unknowns.
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ScholarGateMethoden vergelijken: NMR Spin-Echo · FT-ICR Mass Spectrometry. Geraadpleegd op 2026-06-19 via https://scholargate.app/nl/compare