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Diagram Ellingham×Model Teras Tirus×Kebasaan Sangkur×
BidangKejuruteraan PerlombonganKejuruteraan PerlombonganKejuruteraan Perlombongan
KeluargaProcess / pipelineProcess / pipelineProcess / pipeline
Tahun asal194419761950
PengasasHarold Jeffrey Torreyson EllinghamSzekely, Evans, and SohnPyrometallurgical Practice
JenisGibbs free energy diagram for high-temperature reactionsReaction kinetics model for solid-fluid reactionsSlag composition parameter for controlling roast/smelt conditions
Sumber perintisEllingham, H. J. T. (1944). Reducibility of oxides and sulfides. Journal of the Society of Chemical Industry, 63(5), 125-160. link ↗Szekely, J., Evans, J. W., & Sohn, H. Y. (1976). Gas-solid reactions. Academic Press, New York. link ↗Barnes, J. F., Edwards, C. C., & Sims, R. L. (2010). Copper smelting and refining: pyrometallurgical fundamentals. JOM, 52(12), 38-43. link ↗
AliasGibbs Free Energy Diagram, High-Temperature Reduction DiagramShrinking Unreacted Core Model, SCM, Leaching Kinetics ModelBasicity Index, Slag Chemistry Parameter
Berkaitan333
RingkasanThe Ellingham Diagram, introduced by Harold Ellingham in 1944, is a graphical representation of the Gibbs free energy change for oxide formation and reduction as a function of temperature. It is an essential tool for predicting the thermodynamic feasibility of ore reduction and selecting appropriate reducing agents and temperatures for smelting and roasting operations.The Shrinking Core Model, formalized by Szekely, Evans, and Sohn in 1976, describes the kinetics of chemical reactions between solid ore particles and surrounding fluids (leaching solutions, roasting gases). As the reaction proceeds from the particle surface inward, an unreacted core shrinks while products accumulate in a product layer. The model enables prediction of leaching times and optimization of hydrometallurgical processes.Slag basicity is a measure of the composition of slag formed during smelting and roasting operations. It is typically expressed as the ratio of basic oxides (CaO, MgO) to acidic oxides (SiO2). Basicity controls slag fluidity, viscosity, and reactivity, directly affecting metal recovery, processing temperature, and product quality. It is a critical parameter in copper, nickel, and lead smelting.
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ScholarGateBandingkan kaedah: Ellingham Diagram · Shrinking Core Model · Slag Basicity. Dicapai 2026-06-18 daripada https://scholargate.app/ms/compare