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पेंग-रॉबिन्सन अवस्था समीकरण×UNIFAC×
क्षेत्रअनुप्रयुक्त भौतिकीअनुप्रयुक्त भौतिकी
परिवारProcess / pipelineProcess / pipeline
उद्भव वर्ष19761975
प्रवर्तकDing-Yu Peng and David Bernard RobinsonAage Fredenslund, Russell Jones, John Prausnitz
प्रकारEquation of state; thermodynamic property correlationActivity coefficient model; predictive liquid-phase property method
मौलिक स्रोतPeng, D. Y., & Robinson, D. B. (1976). A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15(1), 59-64. DOI ↗Fredenslund, A., Jones, R. L., & Prausnitz, J. M. (1975). Group-contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal, 21(6), 1086-1099. DOI ↗
उपनामPR-EOS, Peng-Robinson modelUNIFAC predictive model, UNIQUAC functional-group contribution
संबंधित43
सारांशThe Peng-Robinson equation of state is a cubic model that describes the thermodynamic properties of pure fluids and mixtures. Introduced by Ding-Yu Peng and David Bernard Robinson in 1976, it improves upon earlier models (van der Waals, Redlich-Kwong) by better predicting compressibility factors and phase equilibria, especially near the critical point. It is widely used in petroleum engineering, chemical process design, and natural gas calculations.UNIFAC (Universal Functional-group Activity Coefficient) is a predictive model for liquid-phase activity coefficients of multicomponent mixtures. Developed by Fredenslund, Jones, and Prausnitz in 1975, it decomposes molecules into functional groups and uses group interaction parameters to estimate non-ideal behavior. UNIFAC is revolutionary because it can predict phase equilibria for mixtures never experimentally measured, making it invaluable for process design and chemical engineering.
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