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पेंग-रॉबिन्सन अवस्था समीकरण×पीएफआर मॉडल×रिएक्टिव डिस्टिलेशन×
क्षेत्रअनुप्रयुक्त भौतिकीअनुप्रयुक्त भौतिकीअनुप्रयुक्त भौतिकी
परिवारProcess / pipelineProcess / pipelineProcess / pipeline
उद्भव वर्ष197619621995
प्रवर्तकDing-Yu Peng and David Bernard RobinsonOctave LevenspielKlaus Sundmacher
प्रकारEquation of state; thermodynamic property correlationMathematical model for plug-flow reactorIntegrated reaction-separation process model
मौलिक स्रोतPeng, D. Y., & Robinson, D. B. (1976). A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15(1), 59-64. DOI ↗Levenspiel, O. (1999). Chemical Reaction Engineering (3rd ed.). John Wiley & Sons. ISBN: 978-0-471-25424-9Sundmacher, K., & Kienle, A. (2003). Reactive Distillation: Status and Future Directions. Wiley-VCH. ISBN: 978-3-527-30623-9
उपनामPR-EOS, Peng-Robinson modelideal tubular reactor, plug-flow model, PFRintegrated distillation-reaction, reactive column, reaction with separation
संबंधित434
सारांशThe Peng-Robinson equation of state is a cubic model that describes the thermodynamic properties of pure fluids and mixtures. Introduced by Ding-Yu Peng and David Bernard Robinson in 1976, it improves upon earlier models (van der Waals, Redlich-Kwong) by better predicting compressibility factors and phase equilibria, especially near the critical point. It is widely used in petroleum engineering, chemical process design, and natural gas calculations.The PFR (Plug Flow Reactor) model describes the behavior of a tubular reactor in which fluid elements move through as distinct plugs with no axial mixing. Fluid at the inlet is freshly unreacted; as it travels downstream, reactions progress. This idealized model, formalized by Octave Levenspiel alongside CSTR theory, is the opposite extreme: while CSTRs are fully mixed, PFRs have no axial mixing. In practice, PFRs achieve higher conversion than CSTRs for the same residence time and are widely used in the chemical and petroleum industries.Reactive distillation couples reaction and separation in a single column, where reactants are separated from products continuously while simultaneously undergoing reaction on catalytic trays. Pioneered in the 1990s by Klaus Sundmacher and others, this process intensification technique dramatically reduces capital cost, energy consumption, and environmental impact for suitable reactions. It is now industrially proven for esterification, hydration, and transesterification processes.
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