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| UNIFAC× | Peng-Robinsons tilanyhtälö× | |
|---|---|---|
| Tieteenala | Sovellettu fysiikka | Sovellettu fysiikka |
| Menetelmäperhe | Process / pipeline | Process / pipeline |
| Syntyvuosi≠ | 1975 | 1976 |
| Kehittäjä≠ | Aage Fredenslund, Russell Jones, John Prausnitz | Ding-Yu Peng and David Bernard Robinson |
| Tyyppi≠ | Activity coefficient model; predictive liquid-phase property method | Equation of state; thermodynamic property correlation |
| Alkuperäislähde≠ | Fredenslund, A., Jones, R. L., & Prausnitz, J. M. (1975). Group-contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal, 21(6), 1086-1099. DOI ↗ | Peng, D. Y., & Robinson, D. B. (1976). A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15(1), 59-64. DOI ↗ |
| Rinnakkaisnimet | UNIFAC predictive model, UNIQUAC functional-group contribution | PR-EOS, Peng-Robinson model |
| Liittyvät≠ | 3 | 4 |
| Tiivistelmä≠ | UNIFAC (Universal Functional-group Activity Coefficient) is a predictive model for liquid-phase activity coefficients of multicomponent mixtures. Developed by Fredenslund, Jones, and Prausnitz in 1975, it decomposes molecules into functional groups and uses group interaction parameters to estimate non-ideal behavior. UNIFAC is revolutionary because it can predict phase equilibria for mixtures never experimentally measured, making it invaluable for process design and chemical engineering. | The Peng-Robinson equation of state is a cubic model that describes the thermodynamic properties of pure fluids and mixtures. Introduced by Ding-Yu Peng and David Bernard Robinson in 1976, it improves upon earlier models (van der Waals, Redlich-Kwong) by better predicting compressibility factors and phase equilibria, especially near the critical point. It is widely used in petroleum engineering, chemical process design, and natural gas calculations. |
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