Vertaile menetelmiä
Tarkastele valitsemiasi menetelmiä rinnakkain; eroavat rivit korostetaan.
| Syklinen voltammetria× | Krononperimetria× | RDE Koutecky-Levich× | Plasmoniresonanssi pinnassa× | |
|---|---|---|---|---|
| Tieteenala | Spektroskopia | Spektroskopia | Spektroskopia | Spektroskopia |
| Menetelmäperhe | Process / pipeline | Process / pipeline | Process / pipeline | Process / pipeline |
| Syntyvuosi≠ | 1964 | 1954 | 1962 | 1971 |
| Kehittäjä≠ | Randles Semyon Nicholson | Paul Delahay | Veniamin Levich | Erich Kretschmann |
| Tyyppi≠ | Electrochemical technique | Electrochemical technique | Electrochemical technique | Optical technique |
| Alkuperäislähde≠ | Nicholson, R. S., & Shain, I. (1964). Electroanalytical chemistry. Analytical Chemistry, 36(4), 706-723. link ↗ | Bard, A. J., & Faulkner, L. R. (2001). Electrochemical Methods: Fundamentals and Applications. John Wiley & Sons, 2nd edition. link ↗ | Levich, V. G. (1962). Physicochemical Hydrodynamics. Prentice Hall. link ↗ | Kretschmann, E. (1971). Determination of optical constants of metals by excitation of surface plasmons. Zeitschrift für Physik, 241(4), 313-324. link ↗ |
| Rinnakkaisnimet≠ | CV, cyclic voltammetry, electrochemistry | CA, chronoamperometric method | RDE, rotating disk electrode, Koutecky-Levich | SPR, surface plasmon, SPR biosensing |
| Liittyvät | 3 | 3 | 3 | 3 |
| Tiivistelmä≠ | Cyclic Voltammetry (CV) is an electrochemical technique that measures redox reactions by varying the voltage applied to an electrode and monitoring the resulting current. Developed by Nicholson and Shain in 1964, CV is one of the most widely used electrochemical methods, providing rapid information about the redox potentials and electron-transfer kinetics of molecules and materials. | Chronoamperometry (CA) is an electrochemical technique that measures current as a function of time when a potential step is applied to an electrode. Developed by Delahay in the 1950s, CA reveals diffusion-controlled electrochemical processes and enables determination of diffusion coefficients, surface coverage, and kinetic rate constants by analyzing the transient current decay. | Rotating Disk Electrode (RDE) electrochemistry combined with Koutecky-Levich analysis is a powerful electrochemical technique that decouples diffusion-limited and kinetically limited electron-transfer processes. Developed by Levich in the 1960s, RDE enables determination of heterogeneous electron-transfer rate constants and mechanistic information by rotating an electrode to control mass transport. | Surface Plasmon Resonance (SPR) is a real-time, label-free technique for detecting and monitoring biomolecular interactions at a sensor surface by measuring changes in the refractive index caused by ligand binding. Developed by Kretschmann in 1971 and applied to biosensing by Liedberg, Nylander, and Lundström in 1983, SPR is now a gold standard for measuring binding kinetics (association and dissociation rates) and equilibrium binding constants in protein interactions, antibody-antigen recognition, and drug discovery. |
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