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UNIFAC×Ecuación de estado de Peng-Robinson×
CampoFísica aplicadaFísica aplicada
FamiliaProcess / pipelineProcess / pipeline
Año de origen19751976
Autor originalAage Fredenslund, Russell Jones, John PrausnitzDing-Yu Peng and David Bernard Robinson
TipoActivity coefficient model; predictive liquid-phase property methodEquation of state; thermodynamic property correlation
Fuente seminalFredenslund, A., Jones, R. L., & Prausnitz, J. M. (1975). Group-contribution estimation of activity coefficients in nonideal liquid mixtures. AIChE Journal, 21(6), 1086-1099. DOI ↗Peng, D. Y., & Robinson, D. B. (1976). A new two-constant equation of state. Industrial & Engineering Chemistry Fundamentals, 15(1), 59-64. DOI ↗
AliasUNIFAC predictive model, UNIQUAC functional-group contributionPR-EOS, Peng-Robinson model
Relacionados34
ResumenUNIFAC (Universal Functional-group Activity Coefficient) is a predictive model for liquid-phase activity coefficients of multicomponent mixtures. Developed by Fredenslund, Jones, and Prausnitz in 1975, it decomposes molecules into functional groups and uses group interaction parameters to estimate non-ideal behavior. UNIFAC is revolutionary because it can predict phase equilibria for mixtures never experimentally measured, making it invaluable for process design and chemical engineering.The Peng-Robinson equation of state is a cubic model that describes the thermodynamic properties of pure fluids and mixtures. Introduced by Ding-Yu Peng and David Bernard Robinson in 1976, it improves upon earlier models (van der Waals, Redlich-Kwong) by better predicting compressibility factors and phase equilibria, especially near the critical point. It is widely used in petroleum engineering, chemical process design, and natural gas calculations.
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ScholarGateComparar métodos: UNIFAC · Peng-Robinson Equation of State. Recuperado el 2026-06-20 de https://scholargate.app/es/compare