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Standardadditionsmethode×UV/Vis-Spektrophotometrie×
FachgebietAnalytische ChemieAnalytische Chemie
FamilieProcess / pipelineProcess / pipeline
Entstehungsjahr1920s1852
UrheberAnalytical chemistry practiceAugust Beer
Typmatrix-compensating calibration techniqueabsorption measurement technique
Wegweisende QuelleHarris, D. C. (2010). Quantitative Chemical Analysis (8th ed.). Freeman. ISBN: 978-1429218153Beer, A. (1852). Bestimmung der Absorption des rothen Lichts in farbigen Flussigkeiten. Annalen der Physik und Chemie, 86(5), 78–88. DOI ↗
Aliasnamenspiking method, known-addition method, matrix matchingUV-Vis spectroscopy, absorption spectroscopy, colorimetry
Verwandt55
ZusammenfassungThe standard addition method is a quantitative analytical technique that determines the concentration of an unknown analyte by measuring the response before and after adding a known quantity of the analyte (a standard) to the sample itself. This approach compensates for matrix effects and interference from other sample components, making it invaluable when analyzing complex matrices (biological fluids, environmental samples, geological materials) where the sample composition profoundly affects the measured signal. The standard addition method is widely recognized in analytical chemistry as a primary quantification strategy when external calibration is compromised by matrix variability.UV-Vis spectrophotometry is an optical analytical technique that measures the absorption of ultraviolet and visible light (wavelengths 190–900 nm) by substances in solution. Founded on the Beer-Lambert law (developed by August Beer and Pierre Bouguer), it is one of the oldest and most widely used quantitative analytical methods. UV-Vis spectrophotometry is economical, rapid, and applicable to a vast range of organic and inorganic compounds, making it indispensable in pharmaceutical, clinical, environmental, and research laboratories.
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ScholarGateMethoden vergleichen: Standard Addition Method · UV-Vis Spectrophotometry. Abgerufen am 2026-06-18 von https://scholargate.app/de/compare