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| Волтамперометрия× | Кулонометрия× | Потенциометрично титруване× | |
|---|---|---|---|
| Област | Аналитична химия | Аналитична химия | Аналитична химия |
| Семейство | Process / pipeline | Process / pipeline | Process / pipeline |
| Година на възникване≠ | 1922 | 1945 | 1909 |
| Създател≠ | Jaroslav Heyrovsky | James Lingane | Soren Sorensen |
| Тип≠ | electrochemical separation and analysis | electrochemical titration | titration method |
| Основополагащ източник≠ | Nicholson, R. S., & Shain, I. (1965). Theory of stationary electrode polarography for a chemical reaction coupled to electron transfer. Analytical Chemistry, 36(4), 706–723. link ↗ | Lingane, J. J. (1974). Electroanalytical Chemistry (2nd ed.). Interscience Publishers. ISBN: 978-0486409023 | Skoog, D. A., West, D. M., Holler, F. J., & Crouch, S. R. (2014). Fundamentals of Analytical Chemistry (9th ed.). Cengage Learning. ISBN: 978-1133170960 |
| Други названия≠ | electrochemical voltammetry, cyclic voltammetry, CV, differential pulse voltammetry | coulometric titration, electrochemical coulometry, amperes titration | potentiometry, electrochemical titration |
| Свързани | 5 | 5 | 5 |
| Резюме≠ | Voltammetry is an electrochemical analytical technique that studies chemical reactions and properties of substances by measuring the current response as the potential applied to an electrode is systematically varied. Developed by Jaroslav Heyrovsky in the 1920s (polarography), modern voltammetry has become essential for measuring redox potentials, detecting trace analytes, and investigating reaction mechanisms. Variants such as cyclic voltammetry (CV) and differential pulse voltammetry (DPV) offer high sensitivity and selectivity for electrochemically active analytes. | Coulometry is an electrochemical analytical method that determines the concentration of an analyte by measuring the total electric charge (in coulombs) required to oxidize or reduce the analyte completely at an electrode. Developed by James J. Lingane in the 1940s, coulometry is highly accurate because it is based on fundamental constants (Faraday's law) and does not require external standards or calibration curves. This method is particularly valuable for trace analysis, water determination, and analysis of reactive species. | Potentiometric titration is an electrochemical method of analysis that measures the potential difference between a reference electrode and an indicator electrode as a titrant is gradually added to a solution. Developed in the early 20th century, it allows precise determination of the concentration of analytes without requiring visual endpoint indicators. This method is fundamental in analytical chemistry for determining acids, bases, redox species, and metal ions. |
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