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مطيافية الأشعة تحت الحمراء ذات الانعكاس الكلي الموهن (ATR-FTIR)×الرنين النووي المغناطيسي بالتعزيز النووي (NOESY)×
المجالعلم الطيفعلم الطيف
العائلةProcess / pipelineProcess / pipeline
سنة النشأة19611981
صاحب الطريقةJoop FahrenfortRichard Ernst
النوعVibrational spectroscopy techniqueTwo-dimensional pulse sequence
المصدر التأسيسيHarrick, N. J. (1960). Study of physics of internal reflection from metals. Journal of Physics and Chemistry of Solids, 13(2), 143-155. link ↗Aue, W. P., Bartholdi, E., & Ernst, R. R. (1976). Two-dimensional spectroscopy. Application to nuclear magnetic resonance. The Journal of Chemical Physics, 64(5), 2229-2246. DOI ↗
الأسماء البديلةATR-IR, attenuated total reflectance, FTIR spectroscopyNOE spectroscopy, 2D NOESY, NOE NMR
ذات صلة33
الملخصAttenuated Total Reflectance (ATR) Fourier Transform Infrared (FTIR) spectroscopy is a variant of conventional FTIR that measures infrared absorption through evanescent-wave interrogation of samples in direct contact with a high-refractive-index crystal. Developed by Harrick and Fahrenfort in the 1960s, ATR-FTIR is now the dominant form of FTIR spectroscopy, enabling rapid, non-destructive characterization of organic compounds, polymers, coatings, and biological materials without extensive sample preparation.Nuclear Overhauser Enhancement Spectroscopy (NOESY) is a 2D NMR technique that detects through-space dipolar coupling between protons, rather than through-bond scalar coupling. Introduced by Macura and Ernst in 1981, NOESY reveals which protons are spatially close in the three-dimensional structure, independent of bonding connectivity. This makes NOESY invaluable for determining molecular conformation, assigning stereochemistry, and elucidating protein folds.
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ScholarGateقارن الطرق: ATR-FTIR · NOESY. استُرجع بتاريخ 2026-06-20 من https://scholargate.app/ar/compare